STRUCTURAL AND SPECTROSCOPIC CHARACTERIZATION OF V(V)O-IMIDAZOLE COMPLEXES

被引：60

作者：

CORNMAN, CR ^{[1
]}

KAMPF, J ^{[1
]}

PECORARO, VL ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,WILLARD H DOW CHEM SCI LABS,ANN ARBOR,MI 48109

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 11期

关键词：

D O I：

10.1021/ic00037a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex V(v)O(4-(2-(salicylideneamino)ethyl)imidazole)(catecholate), V(v)O(SALIMH)(Cat), is the first crystallographically characterized V(v)O-imidazole compound. The V-51 NMR spectra of this complex and the related materials V(v)O2(SALIMH) and V(v)O(SALIMH)(acetohydroximate) have been compiled. This homologous series shows an unprecedented chemical shift range (1020 ppm) for V(v) complexes with exclusively N and O ligation and illustrates the importance of noninnocent ligands in defining the V-51 NMR shift.

引用

页码：1981 / 1983

页数：3

共 30 条

[1]

[Anonymous], 1990, VANADIUM BIOL SYST P

[2] VANADIUM K-EDGE X-RAY ABSORPTION-SPECTROSCOPY OF BROMOPEROXIDASE FROM ASCOPHYLLUM-NODOSUM [J].

ARBER, JM ;

DEBOER, E ;

GARNER, CD ;

HASNAIN, SS ;

WEVER, R .

BIOCHEMISTRY, 1989, 28 (19) :7968-7973

[3] SIDEROPHORE CHEMISTRY OF VANADIUM - KINETICS AND EQUILIBRIUM OF INTERACTION BETWEEN VANADIUM(IV) AND DESFERRIOXAMINE-B IN AQUEOUS ACIDIC SOLUTIONS [J].

BATINICHABERLE, I ;

BIRUS, M ;

PRIBANIC, M .

INORGANIC CHEMISTRY, 1991, 30 (26) :4882-4887

[4] COORDINATION CHEMISTRY OF VANADIUM IN BIOLOGICAL-SYSTEMS [J].

BUTLER, A ;

CARRANO, CJ .

COORDINATION CHEMISTRY REVIEWS, 1991, 109 (01) :61-105

[5] REACTIVATION OF VANADATE-INHIBITED ENZYMES WITH DESFERRIOXAMINE-B, A VANADIUM(V) CHELATOR [J].

BUTLER, A ;

PARSONS, SM ;

YAMAGATA, SK ;

DELAROSA, RI .

INORGANICA CHIMICA ACTA, 1989, 163 (01) :1-3

[6] BIS-(N-HYDROXY-IMINODIACETATE)VANADATE(IV), A SYNTHETIC MODEL OF AMAVADIN [J].

CARRONDO, MAAFDT ;

DUARTE, MTLS ;

PESSOA, JC ;

SILVA, JAL ;

DASILVA, JJRF ;

VAZ, MCTA ;

VILASBOAS, LF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (17) :1158-1160

[7] CATECHOLATE AND SEMIQUINONE COMPLEXES OF VANADIUM - FACTORS THAT DIRECT CHARGE-DISTRIBUTION IN METAL QUINONE COMPLEXES [J].

CASS, ME ;

GORDON, NR ;

PIERPONT, CG .

INORGANIC CHEMISTRY, 1986, 25 (22) :3962-3967

[8]

CHASTEEN ND, 1990, VANADIUM BIOL SYSTEM

[9] SYNTHESIS AND CHARACTERIZATION OF SOME MIXED-LIGAND OXOVANADIUM(IV) COMPLEXES - THE [LVO]+ CHROMOPHORE, WHERE L = HYDROTRIS(3,5-DIMETHYLPYRAZOLYL)BORATE [J].

COLLISON, D ;

MABBS, FE ;

PASSAND, MA ;

RIGBY, K ;

CLELAND, WE .

POLYHEDRON, 1989, 8 (13-14) :1827-1829

[10] SYNTHETIC, STRUCTURAL, AND PHYSICAL STUDIES OF BIS(TRIETHYLAMMONIUM) TRIS(CATECHOLATO)VANADATE(IV), POTASSIUM BIS(CATECHOLATO)OXOVANADATE(IV), AND POTASSIUM TRIS(CATECHOLATO)VANADATE(III) [J].

COOPER, SR ;

KOH, YB ;

RAYMOND, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (19) :5092-5102

← 1 2 3 →