POLYSTYRENE-SUPPORTED RHCL3 QUATERNARY AMMONIUM ION-PAIR AS A LONG-LIVED, EFFICIENT AND RECYCLABLE CATALYST

被引：13

作者：

SETTYFICHMAN, M

BLUM, J

SASSON, Y

EISEN, M

机构：

[1] HEBREW UNIV JERUSALEM,CASALI INST APPL CHEM,IL-91904 JERUSALEM,ISRAEL

[2] HEBREW UNIV JERUSALEM,DEPT ORGAN CHEM,IL-91904 JERUSALEM,ISRAEL

[3] TECHNION ISRAEL INST TECHNOL,DEPT CHEM,IL-32000 HAIFA,ISRAEL

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 05期

关键词：

D O I：

10.1016/S0040-4039(00)75816-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polymer-supported ion pair, generated from RhCl3 and Dowex(R) 1 anion exchanger was found to be a highly stable, efficient and recyclable catalyst for isomerization of allylic compounds, disproportionation of cyclic 1,3-dienes and trimerization of alkynes.

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页码：781 / 784

页数：4

相关论文

共 13 条

[1] DISPROPORTIONATION AND DEHYDROGENATION OF 1,3-CYCLOHEXADIENES IN THE PRESENCE OF RECYCLABLE RHCL3-QUATERNARY AMMONIUM SALT CATALYSTS [J].

AMER, I ;

ORSHAV, V ;

BLUM, J .

JOURNAL OF MOLECULAR CATALYSIS, 1988, 45 (02) :207-214

[2] OLIGOMERIZATION OF ALKYNES BY THE RHCL3-ALIQUAT 336 CATALYST SYSTEM .1. FORMATION OF BENZENE-DERIVATIVES [J].

AMER, I ;

BERNSTEIN, T ;

EISEN, M ;

BLUM, J ;

VOLLHARDT, KPC .

JOURNAL OF MOLECULAR CATALYSIS, 1990, 60 (03) :313-321

[3] SOME UNUSUAL REACTIONS OF 1,2-BIS(PHENYLETHYNYL)BENZENE WITH SULFUR, CARBON-MONOXIDE AND ALKYL ACETYLENEDICARBOXYLATES [J].

BADRIEH, Y ;

GREENWALD, A ;

SCHUMANN, H ;

BLUM, J .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (03) :667-674

[4] CYCLO-OLIGOMERIZATION AND REARRANGEMENT OF SOME PHENYLATED DIYNES BY THE RHCL3-ALIQUAT-336 AND BY THE H2PTCL6-ALIQUAT-336 CATALYSTS UNDER PHASE-TRANSFER CONDITIONS [J].

BADRIEH, Y ;

BLUM, J ;

AMER, I ;

VOLLHARDT, KPC .

JOURNAL OF MOLECULAR CATALYSIS, 1991, 66 (03) :295-312

[5] ALKYNE HYDRATION PROMOTED BY RHCL3 AND QUATERNARY AMMONIUM-SALTS [J].

BLUM, J ;

HUMINER, H ;

ALPER, H .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 75 (02) :153-160

[6] HYDROGENATION OF ARENES BY THE RHCL3-ALIQUAT-336 CATALYST .4. HYDROGEN-DEUTERIUM EXCHANGE AND OTHER MECHANISTIC FEATURES [J].

BLUM, J ;

AMER, I ;

VOLLHARDT, KPC ;

SCHWARZ, H ;

HOHNE, G .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (13) :2804-2813

[7] SELECTIVE TRANSFER HYDROGENATION OF VARIOUS UNSATURATED FUNCTIONS BY POLYMETHYLHYDROSILOXANE IN THE PRESENCE OF A RECYCLABLE RHODIUM CATALYST [J].

BLUM, J ;

PRIBAR, I ;

ALPER, H .

JOURNAL OF MOLECULAR CATALYSIS, 1986, 37 (2-3) :359-367

[8]

MCQUILLIN FJ, 1963, J CHEM SOC, P5996

[9]

PITTMAN CU, 1982, COMPREHENSIVE ORGANO, V8, P553

[10] SOL-GEL ENCAPSULATED TRANSITION-METAL QUATERNARY AMMONIUM ION-PAIRS AS HIGHLY EFFICIENT RECYCLABLE CATALYSTS [J].

ROSENFELD, A ;

AVNIR, D ;

BLUM, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (06) :583-584