INVERSION OF CONFIGURATION OF ALPHA-TRISUBSTITUTED (NEOPENTYL) TYPE SECONDARY ALCOHOLS

被引：38

作者：

MORIARTY, RM ^{[1
]}

ZHUANG, H ^{[1
]}

PENMASTA, R ^{[1
]}

LIU, K ^{[1
]}

AWASTHI, AK ^{[1
]}

TULADHAR, SM ^{[1
]}

RAO, MSC ^{[1
]}

SINGH, VK ^{[1
]}

机构：

[1] INDIAN INST TECHNOL, DEPT CHEM, KANPUR 208016, UTTAR PRADESH, INDIA

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)61442-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of hindered alpha-trisubstituted optically active secondary alcohols has been converted into their enantiomers by treating the corresponding triflates with KNO2 in DMF in the presence of 18-crown-6 at room temperature.

引用

页码：8029 / 8032

页数：4

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