REACTIVITY OF U-H AND U-C BONDS IN ELECTRON-POOR CYCLOPENTADIENYLURANIUM COMPLEXES - ELECTRONIC EFFECTS

被引：6

作者：

BAUDRY, D

DORMOND, A

ABDALLAOUI, IA

机构：

[1] Laboratoire de Synthèse, d'Electrosynthèse Organométallique associé au CNRS (URA 1685), Faculté des Sciences, Dijon

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 476卷 / 01期

关键词：

URANIUM; CYCLOPENTADIENYL; ELECTRON DEFICIENCY; ELECTRONIC EFFECTS; SYNTHESIS;

D O I：

10.1016/0022-328X(94)84153-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organouranium complexes [(C5H4PPh2)3UX] (X = Cl, (1a) X = Me (1b); X = H (1c)) react with BH3 . SMe2. 1a affords the stable [(C5H4PPh2 . BH3)3UCl] (2a). Both 1b and 1c give finally [(C5H4PPh2 . BH3)3UBH4] (3). The transient [(C5H4PPh2 . BH3)3UMe] (2b) is observed. 2a and 3 may easily be reduced to [(C5H4PPh2 . BH3)3U] (4).

引用

页码：C15 / C17

页数：3

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