ENE-TYPE ADDITION OF ALKENES TO PHENYL VINYLSULFOXIDE

被引：15

作者：

BRICHARD, MH ^{[1
]}

JANOUSEK, Z ^{[1
]}

MERENYI, R ^{[1
]}

VIEHE, HG ^{[1
]}

机构：

[1] LAB CHIM ORGAN,PL L PASTEUR 1,B-1348 LOUVAIN,BELGIUM

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 18期

关键词：

ENE REACTION; VINYLSULFOXIDE; ALKYLATION; TRIFLUOROACETOXYLATION; EPISULFONIUM CATION;

D O I：

10.1016/S0040-4039(00)92228-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phenyl vinylsulfoxide reacts under acylating conditions (TFA, TFAA) with isobutene to give double 'ene" alpha,beta-adduct Propene and other alkenes examined afford a beta-"ene" alkylation accompanied by trifluoroacetoxylation at the same carbon atom.

引用

页码：2511 / 2514

页数：4

共 4 条

[1]

BRICHARD MH, 1991, THESIS U CATHOL LOUV

[2] ADDITIVE PUMMERER REACTIONS OF VINYLIC SULFOXIDES - SYNTHESIS OF GAMMA-HYDROXY-ALPHA,BETA-UNSATURATED ESTERS AND ALPHA-HYDROXYKETONES [J].