STRUCTURES OF FE(III) COMPLEXES WITH EDTA AND EDDDA IN AQUEOUS-SOLUTION BY EXAFS AND XANES

被引：15

作者：

SAKANE, H

WATANABE, I

ONO, K

IKEDA, S

KAIZAKI, S

KUSHI, Y

机构：

[1] RYUKOKU UNIV,FAC SCI & TECHNOL,DEPT MAT CHEM,OTSU,SHIGA 52021,JAPAN

[2] OSAKA UNIV,COLL GEN EDUC,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1990年 / 178卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)88135-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Fe K-edge X-ray absorption spectra of Fe(III) complexes with EDTA (ethylenediaminetetraacetic acid) and EDDDA (ethylenediamine-N,N-diacetic-N,N'-dipropionic acid) in weakly acidic or neutral aqueous solutions are measured. The spectra of powdered crystalline samples of these complexes are also measured as the reference materials. The comparisons of the XANES spectra, including their pre-edge peak, and the EXAFS Fourier transforms conclude that in aqueous solution a seven-coordinate structure is predominant for the Fe(III)-EDTA complex and a six-coordinate one for the Fe(III)-EDDDA complex.

引用

页码：67 / 70

页数：4

共 17 条

[1] VARIABLE CO-ORDINATION OF IRON(III) COMPLEXES IN CO-ORDINATING SOLVENTS
GARBETT, K
LANG, G
WILLIAMS, RJP
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (21): : 3433 - +
[2] HAMOR MJ, 1964, INORG CHEM, V3, P34
[3] KANAMORI H, 1990, B CHEM SOC JPN, V63, P1447
[4] KANAMORI K, 1988, 38TH S COORD CHEM TO
[5] Kennard C., 1967, INORG CHIM ACTA, V1, P347, DOI DOI 10.1016/S0020-1693(00)93200-6
[6] KUSHI Y, 1985, 35TH S COORD CHEM HI
[7] STEREOCHEMISTRY OF ETHYLENEDIAMINETETRAACETATO COMPLEXES .2. STRUCTURE OF CRYSTALLINE RB(FE)OH2)Y)H2O1-3 .3. STRUCTURE OF CRYSTALLINE LI)FE)OH2)Y)2H2O1-3
LIND, MD
HOARD, JL
HAMOR, MJ
HAMOR, TA
[J]. INORGANIC CHEMISTRY, 1964, 3 (01) : 34 - &
[8] NOVOZHILOVA NV, 1973, ZH STRUKT KHIM, V14, P745
[9] EQUILIBRIUM AND KINETIC STUDIES OF THE REACTIONS OF N-SUBSTITUTED (ETHYLENEDIAMINE-N,N',N'-TRIACETATO)AQUACHROMIUM(III) WITH SEVERAL ANIONS
OGINO, H
SHIMURA, M
TANAKA, N
[J]. INORGANIC CHEMISTRY, 1979, 18 (09) : 2497 - 2501
[10] Porai-Koshits M. A., 1987, SOV SCI REV B, V10, P91

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