SILICON-NITROGEN BOND FORMATION BY NUCLEOPHILIC ACTIVATION OF SILICON HYDROGEN-BONDS

被引:25
作者
CORRIU, RJP
LECLERCQ, D
MUTIN, PH
PLANEIX, JM
VIOUX, A
机构
[1] Unité Mixte 044, CNRS/Rhône-Poulenc/USTL, Case, F34095 Montpellier Cédex 5, 007, Place E. Bataillon
关键词
D O I
10.1016/0022-328X(91)83192-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A method of forming Si-N bonds by dehydro-coupling of Si-H and N-H bonds in the presence of a nucleophilic catalyst is reported. The method is useful for the preparation of silylamines and silazanes and for crosslinking of organometallic polymers.
引用
收藏
页码:C1 / C4
页数:4
相关论文
共 13 条
[1]   CATALYTIC SYNTHESIS OF OLIGOSILAZANES .2. [J].
BIRAN, C ;
BLUM, YD ;
GLASER, R ;
TSE, DS ;
YOUNGDAHL, KA ;
LAINE, RM .
JOURNAL OF MOLECULAR CATALYSIS, 1988, 48 (2-3) :183-197
[2]   PRECERAMIC POLYMER PYROLYSIS .1. PYROLYTIC PROPERTIES OF POLYSILAZANES [J].
BLUM, YD ;
SCHWARTZ, KB ;
LAINE, RM .
JOURNAL OF MATERIALS SCIENCE, 1989, 24 (05) :1707-1718
[3]  
BLUM YD, 1986, BETTER CERAMICS THRO, P389
[4]   ENHANCEMENT OF SI-H BOND REACTIVITY IN PENTACOORDINATED STRUCTURES [J].
BOYER, J ;
BRELIERE, C ;
CORRIU, RJP ;
KPOTON, A ;
POIRIER, M ;
ROYO, G .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (03) :C39-C43
[5]   ACTIVATION OF SILICON HYDROGEN, SILICON OXYGEN, SILICON NITROGEN BONDS IN HETEROGENEOUS PHASE - SOME NEW METHODS IN ORGANIC-SYNTHESIS [J].
CORRIU, RJP ;
PERZ, R ;
REYE, C .
TETRAHEDRON, 1983, 39 (06) :999-1009
[6]  
FINK W, 1965, Patent No. 6507996
[7]  
LAINE RM, 1988, ACS SYM SER, V360, P124
[8]  
LEGROW GE, 1987, AM CERAM SOC BULL, V66, P363
[9]  
SEYFERTH D, 1988, ACS SYM SER, V360, P143
[10]  
SEYFERTH D, 1983, J AM CERAM SOC, V66, pC13