PHOTODECOMPOSITION OF 1,2-DIFLUORO-1,2-DI-IODOETHENE - FORMATION OF 1,2-DIFLUOROETHYNE

被引：5

作者：

FRIEDRICH, HB

TARDY, DC

BURTON, DJ

机构：

[1] Department of Chemistry, The University of Iowa, Iowa City

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80473-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Photolysis of trans-1,2-difluoro-1,2-di-iodoethene with 248 nm radiation from an excimer laser yielded difluoroethyne, cis-1,2-difluoro-1,2-di-iodoethene and 1,2,3,4-tetrafluoro-3,4-di-iodocyclobutene. Potential pathways for these products are presented in terms of the energetics of the reaction, and the dependencies of product formation on pressure and extent of conversion are discussed.

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页码：53 / 57

页数：5

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