REDUCTIVE DISPROPORTIONATION OF NO MEDIATED BY COPPER-COMPLEXES - MODELING N2O GENERATION BY COPPER PROTEINS AND HETEROGENEOUS CATALYSTS

被引：116

作者：

RUGGIERO, CE ^{[1
]}

CARRIER, SM ^{[1
]}

TOLMAN, WB ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 08期

关键词：

D O I：

10.1002/anie.199408951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitrito‐O,O‐copper complexes and dinitrogen oxide are the products of the reaction of excess NO with the nitrosyl complexes [LCu(NO)] (L = substituted tris(pyrazolyl)hydroborate), a process that models environmentally important transformations carried out by copper ions in proteins and zeolites. According to the results of kinetic studies, the involvement of dimeric copper species in the rate‐determining step is ruled out, which suggests that NO coupling occurs at a single metal ion. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：895 / 897

页数：3

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