STRUCTURAL AND THEORETICAL EVIDENCE FOR PARTICIPATION OF THE 2ND ACETYLENE PI-ORBITAL IN TRANSITION-METAL ALKYNE COMPLEXES

被引：133

作者：

TATSUMI, K ^{[1
]}

HOFFMANN, R ^{[1
]}

TEMPLETON, JL ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27514

来源：

INORGANIC CHEMISTRY | 1982年 / 21卷 / 01期

关键词：

D O I：

10.1021/ic00131a095

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：466 / 468

页数：3

共 18 条

[1] METAL PERFLUOROALKANE-THIOLATES AND PERFLUOROARENE-THIOLATES .5. REACTIONS OF TRICARBONYL(PI-CYCLOPENTADIENYL)-MOLYBDENUM AND TRICARBONYL(PI-CYCLOPENTADIENYL)-TUNGSTEN THIOLATES AND ACETYLENES [J].

BRATERMAN, PS ;

DAVIDSON, JL ;

SHARP, DWA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (03) :241-245

[2] OLEFIN CO-ORDINATION COMPOUNDS .3. INFRA-RED SPECTRA AND STRUCTURE - ATTEMPTED PREPARATION OF ACETYLENE COMPLEXES [J].

CHATT, J ;

DUNCANSON, LA .

JOURNAL OF THE CHEMICAL SOCIETY, 1953, (OCT) :2939-2947

[3] REACTIONS OF TANTALUM(III) WITH ALKYNES AND NITRILES [J].

COTTON, FA ;

HALL, WT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (17) :5094-5095

[4] LOW-VALENT MOLYBDENUM PORPHYRIN DERIVATIVES - SYNTHESIS AND STRUCTURE OF A PI-BONDED DIPHENYLACETYLENE ADDUCT OF MOLYBDENUM(II) (MESO-TETRA-PARA-TOLYLPORPHYRIN) [J].

DECIAN, A ;

COLIN, J ;

SCHAPPACHER, M ;

RICARD, L ;

WEISS, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (07) :1850-1851

[5]

Dewar M. J. S., 1951, B SOC CHIM FR, V18, pC71, DOI DOI 10.1021/OM0501778

[6] BONDING CAPABILITIES OF TRANSITION-METAL CARBONYL FRAGMENTS [J].

ELIAN, M ;

HOFFMANN, R .

INORGANIC CHEMISTRY, 1975, 14 (05) :1058-1076

[7]

KAMATA M, ORGANOMETALLICS

[8]

KAMATA M, UNPUB

[9] NATURE OF TRIS(ALKYNE)TUNGSTEN MONOCARBONYLS AND RELATED COMPLEXES [J].

KING, RB .

INORGANIC CHEMISTRY, 1968, 7 (05) :1044-&

[10] DEFORMATIONS FROM OCTAHEDRAL GEOMETRY IN D4 TRANSITION-METAL COMPLEXES [J].

KUBACEK, P ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (15) :4320-4332

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