THE MECHANISM OF TITANIUM COMPLEX-CATALYZED REDUCTION OF ARYL HALIDES BY SODIUM-BOROHYDRIDE IS STRONGLY SOLVENT DEPENDENT

被引：26

作者：

LIU, Y ^{[1
]}

SCHWARTZ, J ^{[1
]}

机构：

[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 05期

关键词：

D O I：

10.1021/jo00084a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The titanium complex-catalyzed reduction of arylhalides by sodium borohydride in dimethylacetamide (DMA) or ethers proceeds by electron transfer from a reduced titanium species, yielding an intermediate aryl radical.

引用

页码：940 / 942

页数：3

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