SOLUBILITY PARAMETERS OF POLYMETHACRYLONITRILE, POLY(METHACRYLIC ACID) AND METHACRYLONITRILE METHACRYLIC-ACID COPOLYMER

被引：24

作者：

HO, BC ^{[1
]}

CHIN, WK ^{[1
]}

LEE, YD ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM ENGN,HSIUCHU 30043,TAIWAN

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1991年 / 42卷 / 01期

关键词：

D O I：

10.1002/app.1991.070420112

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The solubility behaviors of polymethyacrylonitrile (PMAN), poly(methacrylic acid) (PMAA), and its random copolymer methacrylonitrile (MAN)/methacrylic acid (MAA) in various solvents were investigated. The results were used in a computer program to obtain a 3‐dimensional representation of the polymer solubility region in the Hansen space. Thus, the values of dispersion (δd,p), polar (δp,p) and hydrogen bonding (δh,p) components of the total solubility parameter (δt,p) were obtained. Comparisons between the experimental results and the estimated values are discussed. Also, prediction for solubility parameter values for MAN/MAA copolymer via their homopolymers, PMAN, and PMAA has been evaluated. Copyright © 1991 John Wiley & Sons, Inc.

引用

页码：99 / 106

页数：8

共 21 条

[1]

[Anonymous], 1991, CRC HDB SOLUBILITY P

[2]

Bernard S., 1972, POLYM LETT, V10, P245

[3] MOLECULAR PROPERTIES OF AMORPHOUS HIGH POLYMERS .1. A CELL THEORY FOR AMORPHOUS HIGH POLYMERS [J].