ELECTROCATALYTIC REDUCTION OF CO2 ON A MODIFIED ELECTRODE WITH LANGMUIR-BLODGETT-FILMS OF NICKEL(II) COMPLEX WITH LONG ALKYL SUBSTITUTED CYCLAM

被引：13

作者：

AKIBA, U

NAKAMURA, Y

SUGA, K

FUJIHIRA, M

机构：

[1] Department of Biomolecular Engineering, Tokyo Institute of Technology, Midori-Ku, Yokohama, 227

来源：

THIN SOLID FILMS | 1992年 / 210卷 / 1-2期

关键词：

D O I：

10.1016/0040-6090(92)90263-B

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A stable monolayer of a macrocyclic complex, Ni(II)-N-docosylcyclam (N-docosylcyclam: 1-docosyl-1,4,8,11-tetraazacyclotetradecane), was formed at the air-water interface, and it was deposited successfully on a glassy carbon electrode using the Langmuir-Blodgett (LB) technique. The cyclic voltammetric behavior of such modified electrodes for CO2 reduction in H2O revealed that the electrocatalytic reduction proceeded at a thermodynamically favorable potential of -1.25 V versus SCE, and the catalysts in the first layer on the electrode were more effective than those in the outer layers.

引用

页码：381 / 383

页数：3

共 7 条

[1] ELECTROCATALYTIC REDUCTION OF CO2 BY NI CYCLAM2+ IN WATER - STUDY OF THE FACTORS AFFECTING THE EFFICIENCY AND THE SELECTIVITY OF THE PROCESS [J].