ASYMMETRIC FUNCTIONALIZATION OF PROCHIRAL 1,3-DIOLS BASED ON AN EFFICIENT 1,6-CHIRAL INDUCTION - THE DIASTEREOSELECTIVE C-O BOND FISSION IN CHIRAL BETA-ARYLSULFINYL ACETAL VIA 2 TYPES OF CHELATION CONTROL

被引：19

作者：

IWATA, C

MAEZAKI, N

MURAKAMI, M

SOEJIMA, M

TANAKA, T

IMANISHI, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 06期

关键词：

D O I：

10.1039/c39920000516

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel asymmetric functionalisation of a prochiral 1,3-diol is accomplished by the diastereoselective C-O bond fission of the chiral beta-arylsulfinyl acetal via two types of chelation controlled transition states (A and C in Scheme 4).

引用

页码：516 / 518

页数：3

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