NOVEL REACTIONS OF ALKYNES ON A COORDINATIVELY UNSATURATED DIRUTHENIUM CENTER BRIDGED BY THIOLATE LIGANDS - SYNTHESES AND CRYSTAL-STRUCTURES OF DINUCLEAR RUTHENACYCLOPENTENYL COMPLEXES

被引：28

作者：

NISHIO, M ^{[1
]}

MATSUZAKA, H ^{[1
]}

MIZOBE, Y ^{[1
]}

HIDAI, M ^{[1
]}

机构：

[1] UNIV TOKYO,DEPT SYNTHET CHEM,TOKYO 113,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

关键词：

D O I：

10.1039/c39930000375

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordinatively unsaturated complex [(eta5-C5Me5)Ru(mu2-SPri)2Ru(eta5-C5Me5)] 1 reacts with HC=CR {R = Tol (p-MeC6H4) or C=CH[CH2]3CH2) to form novel dinuclear ruthenacyclopentenyl complexes 2 and 3, respectively, both of which have been fully characterized by X-ray crystallography.

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页码：375 / 377

页数：3

相关论文

共 15 条

[1] HETEROGENEOUS CATALYSIS OF THE HYDRODESULFURIZATION OF THIOPHENES IN PETROLEUM - AN ORGANOMETALLIC PERSPECTIVE OF THE MECHANISM [J].

ANGELICI, RJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (11) :387-394

[2]

CAUTON L, 1987, J CHEM SOC DA, P895

[3] METAL PERFLUORO-ALKANE-AND-ARENE-THIOLATES .4. REACTIONS OF SOME MANGANESE, IRON, AND COBALT DERIVATIVES WITH ALKYNES [J].

DAVIDSON, JL ;

SHARP, DWA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (21) :2283-2287

[4] PREPARATION AND REACTIONS OF DIRUTHENIUM THIOLATE COMPLEXES [CPSTARRU(MU-SR)3RUCPSTAR] (CPSTAR=ETA-5-C5ME5 R = I-PR, ET, CY, BZ, PH) [J].

DEV, S ;

MIZOBE, Y ;

HIDAI, M .

INORGANIC CHEMISTRY, 1990, 29 (23) :4797-4801

[5] PREPARATION, PROPERTIES, AND SOME REACTIONS OF NOVEL RUTHENIUM THIOLATE COMPLEXES [J].

DEV, S ;

IMAGAWA, K ;

MIZOBE, Y ;

CHENG, GB ;

WAKATSUKI, Y ;

YAMAZAKI, H ;

HIDAI, M .

ORGANOMETALLICS, 1989, 8 (05) :1232-1237

[6]

DuBois M. Rakowski, 1989, CHEM REV, V89, P1

[7] ORGANOTHIOMETALLATE ADDITION-REACTIONS WITH ELECTRONEGATIVE ALKYNES - X-RAY MOLECULAR-STRUCTURES OF [(ETA-5-C5H5)(CO)FEC(O)C(CF3)=CHSME], [(ETA-5-C5H5)(CO)FEC(CF3)=CHS(ME)FE(CO)(ETA-5-C5H5)SME], AND [(ETA-5-C5H5)(CO)MOC(O)C(CF3)C(O)SME] [J].

GUERCHAIS, JE ;

LEFLOCHPERENNOU, F ;

PETILLON, FY ;

KEITH, AN ;

MANOJLOVICMUIR, L ;

MUIR, KW ;

SHARP, DWA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (09) :410-411

[8] 25 YEARS WITH RUTHENIUM [J].

KNOX, SAR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 400 (1-2) :255-272

[9]

KOLLE U, 1992, J ORGANOMET CHEM, V423, pC20

[10] ALKOXY AND ARYLOXY DERIVATIVES OF (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM - X-RAY CRYSTAL-STRUCTURES OF [(ETA-5-C5ME5)RU(MU-OME)]2, [(ETA-5-C5ME5)(CO)RU(MU-OET)]2, AND (ETA-5-C5ME5)RU(ETA-5-2,6-TBU2C6H3O) AND MOLECULAR-ORBITAL ANALYSIS OF [(ETA-5-C5H5)RU(MU-OME)]2 [J].

LOREN, SD ;

CAMPION, BK ;

HEYN, RH ;

TILLEY, TD ;

BURSTEN, BE ;

LUTH, KW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4712-4718