COMMENSURATE FREEZING OF N-ALKANES IN SILICALITE

被引：55

作者：

VANWELL, WJM

WOLTHUIZEN, JP

SMIT, B

VANHOOFF, JHC

VANSANTEN, RA

机构：

[1] EINDHOVEN UNIV TECHNOL,SCHUIT INST CATALYSIS,INORGAN CHEM & CATALYSIS LAB,5600 MB EINDHOVEN,NETHERLANDS

[2] AMSTERDAM SHELL RES BV,KONINKLIJKE SHELL LAB,AMSTERDAM,NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

ALKANES; CATALYSIS; THERMOCHEMISTRY; ZEOLITES;

D O I：

10.1002/anie.199525431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Very surprising desorption behavior from silicalite is shown by n‐hexane and n‐heptane among the n‐alkanes ranging from n‐butane to n‐decane. While n‐hexane and n‐heptane show a two‐step desorption, longer and shorter n‐alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2543 / 2544

页数：2

共 8 条

[1]

DUBININ MM, 1989, IAN SSSR KH, V10, P2333

[2] SILICALITE, A NEW HYDROPHOBIC CRYSTALLINE SILICA MOLECULAR-SIEVE [J].

FLANIGEN, EM ;

BENNETT, JM ;

GROSE, RW ;

COHEN, JP ;

PATTON, RL ;

KIRCHNER, RM ;

SMITH, JV .

NATURE, 1978, 271 (5645) :512-516

[3]

Kraushaar B., 1988, STUD SURF SCI CATAL, V37, P167

[4] ADSORPTION OF HYDROCARBONS AND WATER ON ZSM-5 AND ON ZSM-5 CONVERTED BY DEALUMINATION INTO SILICALITE [J].

LOHSE, U ;

THAMM, H ;

NOACK, M ;

FAHLKE, B .

JOURNAL OF INCLUSION PHENOMENA, 1987, 5 (03) :307-313

[5]

LOHSE U, 1983, CHEM TECH-LEIPZIG, V35, P350

[6] SORPTION AND PACKING OF NORMAL-ALKANE MOLECULES IN ZSM-5 [J].

RICHARDS, RE ;

REES, LVC .

LANGMUIR, 1987, 3 (03) :335-340

[7] TEMPERATURE PROGRAMMED DESORPTION OF SORBATES FROM ZEOLITES .1. CONSTANT COVERAGE, VARIABLE HEATING RATE METHOD [J].

RICHARDS, RE ;

REES, LVC .

ZEOLITES, 1986, 6 (01) :17-25

[8] COMMENSURATE FREEZING OF ALKANES IN THE CHANNELS OF A ZEOLITE [J].

SMIT, B ;

MAESEN, TLM .

NATURE, 1995, 374 (6517) :42-44

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