1,1'-BIS(METHYLPHENYLPHOSPHANYL)FERROCENE - SYNTHESIS AND COMPLEXES WITH THE TETRACARBONYLCHROMIUM FRAGMENT

被引：10

作者：

HERBERICH, GE

MOSS, S

机构：

[1] Institut für Anorganische Chemie, Technische Hochschule Aachen, Aachen

来源：

CHEMISCHE BERICHTE | 1995年 / 128卷 / 07期

关键词：

FERROCENE, 1,1'-BIS(METHYLPHENYLPHOSPHANYL); CHROMIUM; CARBONYL; PHOSPHANE DERIVATIVES;

D O I：

10.1002/cber.19951280706

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,1'-Bis(methylphenylphosphanyl)ferrocene (mppf) (2) was synthesized from dilithioferrocene and PMePh(OC6H4-4-Me). The diastereomers rac-2 and meso-2 were separated by fractional crystallization from ethanol. The tetracarbonyl-chromium complexes (rac-2)Cr(CO)(4) (rac-5) and (meso-2)Cr(CO)(4) (meso-5) were obtained photochemically from hexacarbonylchromium and mppf in near quantitative yield. The structures of rac-2, rac-5, and meso-5 were determined by X-ray crystallographic analysis.

引用

页码：689 / 693

页数：5

共 25 条

[1] Berger S., 1984, 13C NMR SPEKTROSKOPI
[2] SYMMETRICALLY DISUBSTITUTED FERROCENES .1. SYNTHESIS OF POTENTIAL BIDENTATE LIGANDS
BISHOP, JJ
DAVISON, A
KATCHER, ML
LICHTENB.DW
MERRILL, RE
SMART, JC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 27 (02) : 241 - &
[3] Breitmaier E., 1974, 13C NMR SPECTROSCOPY
[4] SIGNS AND MAGNITUDES OF C-13 P-31 SPIN-SPIN COUPLING-CONSTANTS IN TRIPHENYL-PHOSPHINE
BUNDGAARD, T
JAKOBSEN, HJ
[J]. ACTA CHEMICA SCANDINAVICA, 1972, 26 (06): : 2548 - +
[5] 1,1'-BIS[(ALKYL/ARYL)PHOSPHINO]FERROCENES - SYNTHESIS AND METAL-COMPLEX FORMATION - CRYSTAL-STRUCTURE OF 3 METAL-COMPLEXES OF FE(ETA-5-C5H4PPH2)2-
BUTLER, IR
CULLEN, WR
KIM, TJ
RETTIG, SJ
TROTTER, J
[J]. ORGANOMETALLICS, 1985, 4 (06) : 972 - 980
[6] METAL-HYDRIDES FROM CATIONIC RHODIUM(I) CATALYST PRECURSORS - X-RAY STRUCTURE OF [(L-L)HRH(MU-H)3RHH(L-L)]CLO4 [L-L = RAC-FE(ETA-5-C5H4PPHBUT)2]
BUTLER, IR
CULLEN, WR
KIM, TJ
EINSTEIN, FWB
JONES, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (11) : 719 - 721
[7] THE STRUCTURE OF THE 3-2 ADDUCT OF 1,1'-DILITHIOFERROCENE WITH TETRAMETHYLETHYLENEDIAMINE
BUTLER, IR
CULLEN, WR
NI, J
RETTIG, SJ
[J]. ORGANOMETALLICS, 1985, 4 (12) : 2196 - 2201
[8] 13C-H PROTON MAGNETIC RESONANCE SPECTRA OF FERROCENE AND SOME RELATED METALLOCENES
CRECELY, RW
CRECELY, KM
GOLDSTEI.JH
[J]. INORGANIC CHEMISTRY, 1969, 8 (02) : 252 - &
[9] STRUCTURES OF 3 HYDROGENATION CATALYSTS [(P-P)RH(NBD)]CIO4 AND SOME COMPARATIVE RATE STUDIES WHERE (P-P)=(ETA-5-R1R2PC5H4)(ETA-5-R3R4PC5H4)FE (R1=R2=R3=R4=PH,R1=R2=PH,R3=R4=CME,R1=R3=PH,R2=R4=CME3)
CULLEN, WR
KIM, TJ
EINSTEIN, FWB
JONES, T
[J]. ORGANOMETALLICS, 1985, 4 (02) : 346 - 351
[10] FRENZ BA, 1978, ENRAF N0NIUS CAD4 SD

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