LIVING CARBOCATIONIC POLYMERIZATION .16. LIVING CARBOCATIONIC POLYMERIZATION OF STYRENE

被引：74

作者：

FAUST, R

KENNEDY, JP

机构：

[1] Univ of Akron, United States

来源：

POLYMER BULLETIN | 1988年 / 19卷 / 01期

关键词：

Esters--Applications - Polymerization--Cationic Polymerization - Polymers--Molecular Weight;

D O I：

10.1007/BF00255019

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Living carbocationic polymerization of styrene (St) has been achieved by the use of the 1(p-methylphenyl)ethyl acetate (pMePhEtOAc)&middotBCl3 complex in CH3Cl solvent at -30°C using both the IMA and AMI techniques. With phenylethyl acetate (phEtOAc) living polymerization is achieved, however, initiation (cation generation) is slow. Forced termination by pyridine or methanol, or heating to ambient temperature leads to -CH2CH(C6H5)Cl end groups.

引用

页码：21 / 28

页数：8

共 8 条

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