GAS-CHROMATOGRAPHIC CHEMILUMINESCENT DETECTION AND EVALUATION OF PREDICTIVE MODELS FOR IDENTIFYING NITRATED POLYCYCLIC AROMATIC-HYDROCARBONS IN A DIESEL FUEL PARTICULATE EXTRACT

被引：64

作者：

ROBBAT, A ^{[1
]}

CORSO, NP ^{[1
]}

DOHERTY, PJ ^{[1
]}

WOLF, MH ^{[1
]}

机构：

[1] CAMBRIDGE ANALYT ASSOC INC,BOSTON,MA 02215

来源：

ANALYTICAL CHEMISTRY | 1986年 / 58卷 / 09期

关键词：

DIESEL FUELS - Chromatographic Analysis;

D O I：

10.1021/ac00122a032

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A chemiluminescent detector (CD) has been evaluated for the analysis of nitrated polycyclic aromatic hydrocarbons (nitro-PAH) via gas chromatography. The detector responded linearly to most nitro-PAH from 100 ng to 50 pg using the experimental conditions described in the text. The selective detection of nitro-PAH over other hydrocarbons was compared to the relative selectivities of flame ionization detection and detection with electron impact mass spectrometry and negative ion chemical ionization mass spectrometry. Models have been developed that predict the gas chromatographic behavior of nitro-PAH on SE-52.

引用

页码：2078 / 2084

页数：7

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