NON-OXO VANADIUM(IV) COMPLEXES WITH TRIDENTATE DIACIDIC LIGANDS - MOLECULAR-STRUCTURE OF BIS[2.2'-DIHYDRORY-AZOBENZENATO(2-)]VANADIUM(IV)

被引：39

作者：

LUDWIG, E

HEFELE, H

UHLEMANN, E

WELLER, F

KLAUI, W

机构：

[1] UNIV POTSDAM,INST ANORGAN CHEM,D-14415 POTSDAM,GERMANY

[2] UNIV MARBURG,FACHBEREICH CHEM,W-3550 MARBURG,GERMANY

[3] UNIV DUSSELDORF,INST ANORGAN CHEM & STRUKTURCHEM,W-4000 DUSSELDORF,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 01期

关键词：

NON-ORE VANADIUM(IV) COMPLEXES; MASS SPECTRA; CYCLOVOLTAMMETRY; BIS [2,2'-DIHYDROXY-AZOBENZENATO(2)]VANADIUM(IV); TRIGONAL-PRISMATIC STRUCTURE;

D O I：

10.1002/zaac.19956210107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By the reaction of tris (acetylacetonato)vanadium(III) with tridentate diacidic ligands non-ore vanadium(IV) complexes of these ligands were synthesized. The complexes were characterized by mass spectrometry. Electrochemical studies show that the complexes are reversibly oxidized or reduced. Bis[2,2'dihydroxy-azobenzenato(2 -)]vanadium(IV) has a distorted trigonal-prismatic structure. Crystallographic data see ''Inhaltsubersicht''.

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页码：23 / 28

页数：6

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