TEMPLATE SYNTHESIS OF GRAPHITIC NANOTUBULES

被引：149

作者：

PARTHASARATHY, RV ^{[1
]}

PHANI, KLN ^{[1
]}

MARTIN, CLR ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

ADVANCED MATERIALS | 1995年 / 7卷 / 11期

关键词：

D O I：

10.1002/adma.19950071103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ensembles of graphite-based nanotubes (see Fig.) have been produced by extending a template approach successfully used for metals and semiconductors to carbons. The outer and inner diameters of the tubules can be controlled by varying the time allowed for the polymerization of acrylonitrile within the pores of a nanoporous membrane, The polyacrylonitrile nanotubes formed in the pores are subsequently graphitized at high temperatures to form the graphitized nanotubes.

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页码：896 / &

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共 23 条

[1] TEMPLATE SYNTHESIS OF METAL MICROTUBULES [J].

BRUMLIK, CJ ;

MARTIN, CR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :3174-3175

[2] MOLECULAR AND SUPERMOLECULAR ORIGINS OF ENHANCED ELECTRONIC CONDUCTIVITY IN TEMPLATE-SYNTHESIZED POLYHETEROCYCLIC FIBRILS .1. SUPERMOLECULAR EFFECTS [J].

CAI, ZH ;

LEI, JT ;

LIANG, WB ;

MENON, V ;

MARTIN, CR .

CHEMISTRY OF MATERIALS, 1991, 3 (05) :960-967

[3] ELECTRONICALLY CONDUCTIVE POLYMER FIBERS WITH MESOSCOPIC DIAMETERS SHOW ENHANCED ELECTRONIC CONDUCTIVITIES [J].

CAI, ZH ;

MARTIN, CR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) :4138-4139

[4] LARGE-SCALE SYNTHESIS OF CARBON NANOTUBES [J].

EBBESEN, TW ;

AJAYAN, PM .

NATURE, 1992, 358 (6383) :220-222

[5] INTRAZEOLITE ASSEMBLY AND PYROLYSIS OF POLYACRYLONITRILE [J].

ENZEL, P ;

ZOLLER, JJ ;

BEIN, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (08) :633-635

[6] TEMPLATE SYNTHESIS OF INFRARED-TRANSPARENT METAL MICROCYLINDERS - COMPARISON OF OPTICAL-PROPERTIES WITH THE PREDICTIONS OF EFFECTIVE MEDIUM THEORY [J].

FOSS, CA ;

TIERNEY, MJ ;

MARTIN, CR .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (22) :9001-9007

[7] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[8] ELECTROCHEMICAL FABRICATION OF CADMIUM CHALCOGENIDE MICRODIODE ARRAYS [J].

KLEIN, JD ;

HERRICK, RD ;

PALMER, D ;

SAILOR, MJ ;

BRUMLIK, CJ ;

MARTIN, CR .

CHEMISTRY OF MATERIALS, 1993, 5 (07) :902-904

[9]

KROSCHWITZ JI, 1993, ENCY CHEM TECHNOLOGY, V5, P4

[10] FORMATION OF HIGHLY ORIENTATED GRAPHITE FROM POLYACRYLONITRILE BY USING A TWO-DIMENSIONAL SPACE BETWEEN MONTMORILLONITE LAMELLAE [J].

KYOTANI, T ;

SONOBE, N ;

TOMITA, A .

NATURE, 1988, 331 (6154) :331-333