FORMATION OF CYCLOPENTENONE UPON PHOTOOXIDATION OF THE CYCLOPROPYL (CYCLO-C3H5) CARBYNE COMPLEX [(ETA-5-C5H5)(P(OME)3)(CO)WC(CYCLO-C3H5)]

被引：17

作者：

KINGSBURY, KB ^{[1
]}

CARTER, JD ^{[1
]}

MCELWEEWHITE, L ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 08期

关键词：

D O I：

10.1039/c39900000624

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：624 / 625

页数：2

共 14 条

[1]

ANDERSON SN, 1973, J CHEM SOC CHEM COMM, P163

[2] Reactions of co-ordinated ligands. Part 45. Ligand displacement and oxidative reactions of the carbyne complex [Mo( CCH2But){P(OMe)3}2(eta-C5H5)]; crystal and molecular structures of [Mo{eta 3-RN=C - C(CH2But)- C=NR}-(CNR)2(eta-C5H5)](R=2,6-Me2C6H3), [Mo(C=CHBut)I{P(OMe)3}2(eta-C5H5)], and [M o{=C(CH2But)P(O)(OMe)2}{P(OMe)3}(eta-C5H5)] [J].

BAKER, PK ;

BARKER, GK ;

GILL, DS ;

GREEN, M ;

ORPEN, AG ;

WILLIAMS, ID ;

WELCH, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (07) :1321-1331

[3] REACTIVITY OF TRIETHYL PHOSPHITE WITH TETRACHLOROMETHANE - ELECTRON-TRANSFER VERSUS IONIC SUBSTITUTION ON POSITIVE HALOGEN [J].

BAKKAS, S ;

JULLIARD, M ;

CHANON, M .

TETRAHEDRON, 1987, 43 (03) :501-512

[4] THE REACTIONS OF AN AMBIDENT LITHIUM MOLYBDENUMVINYLIDENE COMPLEX WITH ELECTROPHILES - NOVEL FORMATION OF A 1,3-DIENE COMPLEX AND EVIDENCE FOR INTRAMOLECULAR CARBON-HYDROGEN ACTIVATION ON PHOTOLYSIS OF A CARBYNE COMPLEX [J].

BEEVOR, RG ;

FREEMAN, MJ ;

GREEN, M ;

MORTON, CE ;

ORPEN, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (02) :68-70

[5] REACTIONS OF METAL-CARBONYL DERIVATIVES .24. MECHANISM OF HALOGENATION OF THE NON-BRIDGED METAL-METAL BONDED DERIVATIVES, [(M(ETA-C5H5)(CO)2L)2] (M = MO OR W, L = CO-M = MO, L = P(OCH3)3) [J].

BURCKETTSTLAURENT, JCTR ;

FIELD, JS ;

HAINES, RJ ;

MCMAHON, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 181 (01) :117-130

[6]

CARTER JG, UNPUB

[7] THE ROAD FROM ALKYNES TO MOLYBDENUM CARBON MULTIPLE BONDS [J].

GREEN, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 300 (1-2) :93-109

[8] ELECTROCHEMICAL OXIDATION-REDUCTION OF ORGANO-METALLIC COMPLEXES - EFFECT OF THE OXIDATION-STATE ON THE PATHWAYS FOR REDUCTIVE ELIMINATION OF DIALKYLIRON COMPLEXES [J].

LAU, W ;

HUFFMAN, JC ;

KOCHI, JK .

ORGANOMETALLICS, 1982, 1 (01) :155-169

[9] PHOTOOXIDATION OF (ETA-5-C5H5)[P(OME)3]2MO=CPH IN CHCL3 - INTERMEDIACY OF A 17-ELECTRON CATIONIC METAL CARBYNE [J].

LEEP, CJ ;

KINGSBURY, KB ;

MCELWEEWHITE, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (22) :7535-7536

[10] OXIDATIVELY PROMOTED ALKYL TO ACYL MIGRATORY INSERTION REACTIONS - A THERMODYNAMIC ASSESSMENT FOR IRON METHYL COMPLEXES [J].

MAGNUSON, RH ;

MEIROWITZ, R ;

ZULU, S ;

GIERING, WP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5790-5791

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