OXIDATION OF PRIMARY AROMATIC-AMINES TO NITRO-DERIVATIVES CATALYZED BY IRON(III) AND MANGANESE(III) TETRAARYL PORPHYRINS

被引：29

作者：

TOLLARI, S

VERGANI, D

BANFI, S

PORTA, F

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM INORGAN,VIA VENEZIAN 21,I-20133 MILAN,ITALY

[2] UNIV MILAN,CTR CNR,I-20133 MILAN,ITALY

[3] CNR,CTR SINTESI STEREOCHIM SPECIALI SYST ORGAN,I-20133 MILAN,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期

关键词：

D O I：

10.1039/c39930000442

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of primary aromatic amines to the corresponding nitro derivatives has been observed in catalytic systems (turnovers/hour up to 18 000) containing tert-butyl hydroperoxide and metallo-tetraaryl porphyrins (metal = Fe(III) or Mn(III)) in the presence of heterocyclic nitrogen bases acting as axial ligands.

引用

页码：442 / 444

页数：3

共 25 条

[1] SYNERGISTIC EFFECT OF LIPOPHILIC CARBOXYLIC-ACIDS AND HETEROCYCLIC AXIAL LIGANDS IN ALKENE EPOXIDATION BY HYDROGEN-PEROXIDE CATALYZED BY MANGANESE(III) TETRA-ARYL PORPHYRINS
ANELLI, PL
BANFI, S
MONTANARI, F
QUICI, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (12) : 779 - 780
[2] BALDWIN JE, 1984, TOP CURR CHEM, V121, P181
[3] INVESTIGATION ON FACTORS RULING CATALYTIC EFFICIENCY AND CHEMICAL-STABILITY OF MN(III) PORPHYRINS IN HOCL OLEFIN EPOXIDATION - CONDITIONS FOR PRACTICAL APPLICATION
BANFI, S
MONTANARI, F
QUICI, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (08) : 1850 - 1859
[4] BANFI S, 1990, GAZZ CHIM ITAL, V120, P123
[5] BANFI S, 1990, CHIM IND, V72, P304
[6] MONOOXYGENASE-LIKE OXIDATION OF HYDROCARBONS BY H2O2 CATALYZED BY MANGANESE PORPHYRINS AND IMIDAZOLE - SELECTION OF THE BEST CATALYTIC-SYSTEM AND NATURE OF THE ACTIVE OXYGEN SPECIES
BATTIONI, P
RENAUD, JP
BARTOLI, JF
REINAARTILES, M
FORT, M
MANSUY, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) : 8462 - 8470
[7] BRUICE TC, 1988, MOL STRUCT ENERG, V9, P227
[8] CENINI S, 1982, J MOL CATAL, V15, P297, DOI 10.1016/0304-5102(82)80023-0
[9] METALLOPORPHYRINS AS MODELS FOR THE CYTOCHROMES-P-450
GUNTER, MJ
TURNER, P
[J]. COORDINATION CHEMISTRY REVIEWS, 1991, 108 (02) : 115 - 161
[10] Hill C. L., 1989, ACTIVATION FUNCTIONA

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