SOLUTION STABILIZED MONOMERIC DIALKYL-ALUMINUM AND DIALKYL-GALLIUM SPECIES, [M2-C(SIME3)2C5H4N)] FROM REDUCTION OF MR2CL - CRYSTAL-STRUCTURE OF GAR2CL

被引：27

作者：

KYNAST, U

SKELTON, BW

WHITE, AH

HENDERSON, MJ

RASTON, CL

机构：

[1] GRIFFITH UNIV,DIV SCI & TECHNOL,NATHAN,QLD 4111,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT PHYS & INORGAN CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 384卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)87072-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of MR2Cl, M Al or Ga, R = 2-C(SiMe3)2C5H4N, in THF yields the paramagnetic dialkylmetal species, [MR2]., which in the absence of solvent yields diamagnetic material shown to contain reductively coupled pyridyl groups by isolation of the corresponding 4,4′-dipyridyl after hydrolysis and oxidation. An X-ray diffraction study of [GaR2Cl] has shown the metal to be in a distorted trigonal bipyramidal environment with apical N-centres. © 1990.

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页码：C1 / C5

页数：5

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