AN ENANTIOSELECTIVE SYNTHESIS OF THE SPIROTETRONATE SUBUNIT OF KIJANOLIDE

被引：32

作者：

MARSHALL, JA

XIE, SP

机构：

[1] Department of Chemistry, University of South Carolina, Columbia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 11期

关键词：

D O I：

10.1021/jo00037a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder adduct 11 of alpha-bromoacrolein and triene 9 was converted to spirotetronate 21 through a sequence involving Pummerer rearrangement of the derived sulfoxide 16, oxidation of the resulting aldehyde 17, and Dieckmann cyclization of the diester 19 followed by in situ quench with MOMCl.

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页码：2987 / 2989

页数：3

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