PLANAR CHIRAL SYSTEMS .1. OPTICAL RESOLUTION OF [2.2]PARACYCLOPHANES BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY ON TRIS(3,5-DIMETHYLPHENYLCARBAMATES) OF CELLULOSE AND AMYLOSE

被引：51

作者：

HOPF, H ^{[1
]}

GRAHN, W ^{[1
]}

BARRETT, DG ^{[1
]}

GERDES, A ^{[1
]}

HILMER, J ^{[1
]}

HUCKER, J ^{[1
]}

OKAMOTO, Y ^{[1
]}

KAIDA, Y ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 04期

关键词：

Resolution; optical / Stationary phase; Chiral / Anylose carbamates / Celluslose carbamates / [3.2]Paracyclophanes; functionalized;

D O I：

10.1002/cber.19901230432

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optical resolution of 22 [2,2]paracyclophane derivatives was examined by high‐performance liquid chromatography (HPLC) using tris(3,5‐dimethylphenylcarbamates) of cellulose and amylose as chiral stationary phases. Most compounds were completely separated into enantiomers at least on one of the stationary phases. The preparation of hte new cyclophane derivatives 10, 11, 12, 14, 16, and 19 as wel as a new procedure for the synthesis of 4‐fluoro‐[2,2]paracyclophane (3) are described. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：841 / 845

页数：5

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