THE CHEMISTRY OF 3-TRIFLUOROMETHYL-PERFLUORO-AZA-2-BUTENE AND THE SYNTHESIS OF A NEW OXAZIRIDINE - 3,3-BISTRIFLUOROMETHYL-2-TRIFLUOROMETHYLOXAZIRIDINE

被引：11

作者：

BRAGANTE, L ^{[1
]}

DESMARTEAU, DD ^{[1
]}

机构：

[1] CLEMSON UNIV, HOWARD L HUNTER CHEM LAB, CLEMSON, SC 29634 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 53卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)82340-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some reactions of (CF3)2C = NCF3 1 (3-trifluoromethyl-perfluoro-aza-2-butene) are reported including the isomerisation to (CF3)2CFN = CF2 3 (3-trifluoromethyl-perfluoro-2-aza-1-butene) and the formation of (CF3)2CFN(Br)CF3 5 (N-perfluoroisopropyl-N-trifluoromethyl-N-bromoamine). The synthesis and characterization of [GRAPHICS] 2 (3,3-bistrifluoromethyl-2-trifluoromethyl-oxaziridine) from 1 is also reported along with its thermal rearrangement to CF3C(O)N(CF3)2 6 (bistrifluoromethyl-trifluoroacetamide) and some selective organic oxidations with 2.

引用

页码：181 / 197

页数：17

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