SYNTHESES OF POLYMERS CONTAINING PENDANT NORBORNADIENE DERIVATIVES BY A PHASE-TRANSFER CATALYSIS AND THEIR PHOTOCHEMICAL VALENCE ISOMERIZATION

被引：24

作者：

NISHIKUBO, T

SAHARA, A

SHIMOKAWA, T

机构：

来源：

POLYMER JOURNAL | 1987年 / 19卷 / 08期

关键词：

CATALYSIS;

D O I：

10.1295/polymj.19.991

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this paper, the authors report the successful syntheses of a polymer containing a pendant NB moiety by substitution reactions of PCMS with potassium salts of 2,5-norbornadiene-2,3-dicarboxylic acid (NBDA) and 3-(phenyl)norbornadiene-2-carboxylic acid (PNBA) using PTC. Also the rate of photochemical valence isomerization of the pendant NB moieties to the QC moieties and the rate of catalytic reversion of QC moieties to the NB moieties are evaluated.

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页码：991 / 994

页数：4

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