SYNTHESIS AND CHARACTERIZATION OF NOVEL TRIANGULAR COPPER(I) COMPLEXES CONTAINING THE TRINUCLEAR MOIETY CU-3(MU-DPPM)(3) (DPPM=BIS(DIPHENYLPHOSPHINO)METHANE) AND TRIPLY BRIDGING ALKOXIDE AND THIOLATE LIGANDS

被引：9

作者：

DIEZ, J

GAMASA, MP

GIMENO, J

机构：

[1] Instituto de Química Organometálica Enrique Moles, Departmento de Química Orgánica e Inorgánica, Facultad de Química

来源：

POLYHEDRON | 1995年 / 14卷 / 06期

关键词：

D O I：

10.1016/0277-5387(94)00307-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel cationic trinuclear alkoxide copper(I) complexes of the type [Cu-3(mu(3)-OR)(mu(3)-Cl)(mu-dppm)(3)][BF4] (R = 2,4,6-(t)Bu(3)C(6)H(2), 2,6-(t)Bu(2)C(6)H(3), 2,6-(t)Bu(2)-p-MeC(6)H(2), p-MeC(6)H(4)) and [Cu-3(mu(3)-XR)(2)(mu-dppm)(3)][BF4] (R = p-MeC(6)H(4); X = O, S) have been obtained by reaction of [Cu-3(mu(3)-Cl)(2)(mu-dppm)(3)][BF4] with the sodium derivative of the corresponding alcohol or thiol. A high yield method for the synthesis of the trinuclear copper(I) precursor complex, based on the reaction of [Cu-2(mu-AcO)(mu-dppm)(2)][BF4] and Me(3)SiCl, is also described. IR, H-1 and P-31 {H-1} NMR data are discussed.

引用

页码：741 / 745

页数：5

共 14 条

[1] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF NEW COPPER-COMPLEXES AND THE COPPER BARIUM ALKOXIDE COMPLEX BACU4(OC(R)C(H)C(R)O)4(OR')2(HOR')4 (R = C(CH3)3, R = CH2CH2OCH3) [J].

BIDELL, W ;

SHKLOVER, V ;

BERKE, H .

INORGANIC CHEMISTRY, 1992, 31 (26) :5561-5571

[2] HETERONUCLEAR ALKOXIDE COMPOUNDS CONTAINING COPPER AND ALKALINE-EARTH METALS [J].

BIDELL, W ;

BOSCH, HW ;

VEGHINI, D ;

HUND, HU ;

DORING, J ;

BERKE, H .

HELVETICA CHIMICA ACTA, 1993, 76 (01) :596-606

[3] SYNTHESIS AND PROPERTIES OF BIS(TERT-BUTYL)METHOXIDES OF CHROMIUM(III,IV), MANGANESE(II), IRON(III), COBALT(II), AND COPPER(I) - THE CRYSTAL AND MOLECULAR-STRUCTURES OF LITHIUM TETRAKIS[BIS(TERT-BUTYL)METHOXO]CHROMATE(III)-TETRAHYDROFURAN (1-1), TETRAKIS[BIS(TERT-BUTYL)METHOXO]CHROMIUM(IV), AND LITHIUM TETRAKIS[BIS(TERT-BUTYL)METHOXO]FERRATE(III)-BIS(TERT-BUTYL)METHANOL (1-1)O] [J].

BOCHMANN, M ;

WILKINSON, G ;

YOUNG, GB ;

HURSTHOUSE, MB ;

ABDULMALIK, KM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (10) :1863-1871

[4] CATIONIC TRINUCLEAR COPPER(I) COMPLEX - STRUCTURE OF 1-1 DERIVATIVE OF CUCL WITH BIS-(DIPHENYLPHOSPHINO)METHANE [J].

BRESCIANI, N ;

MARSICH, N ;

NARDIN, G ;

RANDACCI.L .

INORGANICA CHIMICA ACTA, 1974, 10 (03) :L5-L6

[5]

Cotton FA, 1993, MULTIPLE BONDS METAL

[6] SYNTHESIS AND CHARACTERIZATION OF TRIANGULO COPPER(I) COMPLEXES CONTAINING MONOCAPPING AND BICAPPING SYSTEMS OF ASYMMETRIC MU(3)-ETA(1)-ACETYLIDE LIGANDS - MOLECULAR-STRUCTURES OF [CU3(MU(3)-ETA(1)-CCPH)(MU-DPPM)3][BF4]2, [CU3(MU(3)-ETA(1)-CCPH)2(MU-DPPM)3][BF4], AND [CU3(MU(3)-ETA(1)-CCPH)(MU(3)-CL)(MU-DPPM)3][BF4][DPPM=BIS(DIPHENYLPHOSPHINO)METHANE] [J].

DIEZ, J ;

GAMASA, MP ;

GIMENO, J ;

LASTRA, E ;

AGUIRRE, A ;

GARCIAGRANDA, S .

ORGANOMETALLICS, 1993, 12 (06) :2213-2220

[7] [CU3(MU-3-ETA-1-C=CPH)2(MU-PH2PCH2PPH2)3][BF4], A TRIANGULO COPPER(I) COMPLEX WITH AN UNPRECEDENTED BICAPPING SYSTEM OF 2 ASYMMETRIC MU-3-ETA-1-ACETYLIDE LIGANDS [J].

DIEZ, J ;

GAMASA, MP ;

GIMENO, J ;

AGUIRRE, A ;

GARCIAGRANDA, S .

ORGANOMETALLICS, 1991, 10 (02) :380-382

[8] SYSTEMATIC SYNTHESIS OF TRIPLY BRIDGED BINUCLEAR COPPER(I) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINO)METHANE (DPPM) BRIDGING LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [CU2(MU-DPPM)2(MU-6-METHYLPYRIDIN-2-OLATE]BF4 AND [CU2(MU-DPPM)-(MU-6-METHYLPYRIDIN-2-OLATE)2] [J].

DIEZ, J ;

GAMASA, P ;

GIMENO, J ;

LANFRANCHI, M ;

TIRIPICCHIO, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03) :1027-1033

[9] SYNTHESIS AND CRYSTAL-STRUCTURE OF [CU3(MU-3-ETA-1-C=CPH)(MU-DPPM)3][BF4]2, A TRICOPPER(I) COMPLEX CONTAINING A MU-3-ETA-1 ACETYLIDE GROUP AND 3 BIS(DIPHENYLPHOSPHINO)METHANE (DPPM) BRIDGING LIGANDS [J].

GAMASA, MP ;

GIMENO, J ;

LASTRA, E ;

AGUIRRE, A ;

GARCIAGRANDA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 378 (02) :C11-C14

[10] CONCERNING THE STRUCTURE AND STABILITY OF A COPPER(I) ALKOXY CARBONYL [J].

GEERTS, RL ;

HUFFMAN, JC ;

FOLTING, K ;

LEMMEN, TH ;

CAULTON, KG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (11) :3503-3506

← 1 2 →