VIBRATIONAL SELECTIVITY IN THE SINGLE-PHOTON INFRARED PHOTOCHEMISTRY OF MATRIX-ISOLATED 2-FLUOROETHANOL

被引：17

作者：

SHIRK, JS

MARQUARDT, CL

机构：

[1] Naval Research Laboratory, Washington

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 92卷 / 12期

关键词：

D O I：

10.1063/1.458209

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Relative quantum efficiencies for the IR-induced Gg′ to T1 conformer interconversion of 2-fluoroethanol in solid argon are reported. Laser excitation was used to investigate ten vibrational bands of 2-fluoroethanol with frequencies between 952 and 7121 cm-1. Three bands of the deuterated (OD) analog were also investigated using laser and filtered glower excitation. Deviations of the quantum efficiencies from a smooth, monotonic function of energy were significantly larger than the experimental uncertainties. Anomalously high quantum efficiencies were found for modes with strong coupling to the COH torsion.

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页码：7234 / 7240

页数：7

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