PALLADIUM-CATALYZED ASYMMETRIC ALKYLATION VIA PI-ALLYL INTERMEDIATE - ACETAMIDOMALONATE ESTER AS A NUCLEOPHILE

被引：81

作者：

YAMAGUCHI, M

SHIMA, T

YAMAGISHI, T

HIDA, M

机构：

[1] Department of Industrial Chemistry, Faculty of Engineering, Tokyo Metropolitan University, Tokyo, 158, Fukasawa

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)97803-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with sodium salt of acetamidomalonate ester has been carried out in the presence of a palladium catalyst containing (S)-BINAP to give a chiral α-allyl-αacetamidomalonate ester derivative of high optical purity (94±1% ee). © 1990.

引用

页码：5049 / 5052

页数：4

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