ENANTIOSELECTIVE ADDITION OF AROMATIC THIOLS TO A KETENE

被引：54

作者：

FEHR, C

STEMPF, I

GALINDO, J

机构：

[1] Firmenich SA, Research Laboratories, Geneva, CH-1211

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High enantioselectivities, even though 95% of the protons come from an achiral source are obtained in the reactions of 1 with lithiated aromatic thiols like 2 in the presence of 5 mol% of the chiral catalyst 3. Ar = Ph, 2-naphthyl, p-ClC6H4.

引用

页码：1044 / 1046

页数：3

共 17 条

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