SYNTHESES OF 6N(N'-FORMYL-D-PHENYLALANYL)-DEOXYAMINO-BETA-CYCLODEXTRIN AND 6N(N'-FORMYL-L-PHENYLALANYL)-DEOXYAMINO-BETA-CYCLODEXTRIN AND THEIR INCLUSION BEHAVIOR

被引：18

作者：

TAKAHASHI, K

OHTSUKA, Y

NAKADA, S

HATTORI, K

机构：

[1] Department of Industrial Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics, Atsugi, Kanagawa

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1991年 / 10卷 / 01期

关键词：

CYCLODEXTRIN; DIASTEREOMER; INTRAMOLECULAR COMPLEX;

D O I：

10.1007/BF01041640

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

6N(N'-formyl-D-phenylalanyl)-deoxyamino-beta-cyclodextrin and 6N(N'-formyl-L-phenylalanyl)-deoxyamino-beta-cyclodextrin (I and II) were prepared. These new hosts formed 'intramolecular host-guest complexes' and included naphthyl derivatives preferentially with a stoichiometry of 1:1. The inclusion behavior was different between I and II because the cavity shape formed with the CD cavity and the phenylalanine moiety of I was different from that of II.

引用

页码：63 / 68

页数：6

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