STRUCTURE OF (1-[(2-HYDROXYPHENYL)IMINOMETHYL]NAPHTHALEN-2-OLATO-O,O',N)-PIPERIDINENICKEL(II)

被引：17

作者：

ELERMAN, Y

PAULUS, EF

FUESS, H

机构：

[1] HOECHST AG,W-6230 FRANKFURT 80,GERMANY

[2] TH DARMSTADT,FACHBEREICH MAT WISSENSCH,W-6100 DARMSTADT,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190007077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ni(C5H11N)(C17H11NO2)], M(r) = 405.12, monoclinic, P2(1)/n, a = 10.471 (1), b = 15.524 (2), c = 12.554 (1) angstrom, beta = 113.07 (1)degrees, V = 1877.5 angstrom 3, Z = 4, F(000) = 848, D(m) = 1.43 Mg m-3 (pycnometrically), D(x) = 1.433 Mg m-3, Mo K-alpha = 0.7107 angstrom, mu = 1.043 mm-1, T = 293 K, R = 0.138, wR = 0.042 for 3241 unique diffractometer data [I > 1-sigma(I)]. Nickel is in a slightly distorted square-planar environment of two oxygens [1.804(4) and 1.830(4) angstrom] and two nitrogens [1.848(4) and 1.947(4) angstrom] with O-Ni-N angles between 87.6(2) and 95.1 (2)degrees. Ni is 0.033 angstrom out of the plane of its ligands.

引用

页码：70 / 72

页数：3

共 6 条

[1] SYNTHESIS, CRYSTAL-STRUCTURE, AND EHMO CALCULATIONS FOR THE NICKEL(II) COMPLEXES OF IMINES DERIVED FROM SALICYLALDEHYDE, 2-HYDROXY-1-NAPHTHALDEHYDE, AND 3-HYDROXY-2-NAPHTHALDEHYDE [J].