ESTER ELIMINATION VERSUS LIGAND-EXCHANGE - THE ROLE OF THE SOLVENT IN TIN-OXO CLUSTER-BUILDING REACTIONS

被引：32

作者：

CARUSO, J

HAMPDENSMITH, MJ

RHEINGOLD, AL

YAP, G

机构：

[1] UNIV NEW MEXICO,DEPT CHEM,ALBUQUERQUE,NM 87131

[2] UNIV NEW MEXICO,CTR MICROENGINEERED CERAM,ALBUQUERQUE,NM 87131

[3] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ester elimination between Sn(OBu(t))(4) and Sn(OAc)(4) in refluxing toluene yields Sn-6(O)(6)(OCMe(3))(6)(O(2)CMe)(6) which is characterized in solution and in the solid state by single-crystal X-ray diffraction; reaction of the same species in pyridine results in the formation of the ligand exchange products, Sn(OBu(t))(x)(OAc)(4-x) where x = 1-3.

引用

收藏

页码：157 / 158

页数：2

相关论文

共 18 条

[1] ACETATES AND ACETATO COMPLEXES .4. CRYSTAL AND MOLECULAR-STRUCTURE OF TIN TETRAACETATE [J].

ALCOCK, NW ;

TRACY, VL .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (JAN) :80-83

[2] METAL OXIDE ALKOXIDE POLYMERS .5. HYDROLYSIS OF SOME ALKOXIDES OF TIN (IV), CERIUM (IV), AND URANIUM (V) [J].

BRADLEY, DC ;

HOLLOWAY, H .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1962, 40 (06) :1176-&

[3] ORGANOSILYLOXY-DERIVATIVES OF METALS .1. ALKYLSILYLOXYDERIVATIVES OF TITANIUM, ZIRCONIUM, NIOBIUM, AND TANTALUM [J].

BRADLEY, DC ;

THOMAS, IM .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (NOV) :3404-3411

[4]

BRINKER CJ, 1990, SOL GEL SCI PHYSICS

[5]

CARUSO J, 1994, IN PRESS INORG CHEM

[6]

CARUSO J, UNPUB INORG CHEM

[7] CHEMICAL ASPECTS OF SOLUTION ROUTES TO PEROVSKITE-PHASE MIXED-METAL OXIDES FROM METAL-ORGANIC PRECURSORS [J].

CHANDLER, CD ;

ROGER, C ;

HAMPDENSMITH, MJ .

CHEMICAL REVIEWS, 1993, 93 (03) :1205-1241

[8] NEW DRUM AND LADDER ORGANOOXOTIN CARBOXYLATES [J].

CHANDRASEKHAR, V ;

SCHMID, CG ;

BURTON, SD ;

HOLMES, JM ;

DAY, RO ;

HOLMES, RR .

INORGANIC CHEMISTRY, 1987, 26 (07) :1050-1056

[9] CHEMICAL APPROACHES TO ADVANCED MATERIALS - FOREWORD [J].

CHISHOLM, MH ;

HAMPDENSMITH, MJ .

POLYHEDRON, 1994, 13 (08) :1109-1109

[10] THE SINGLE-SOURCE PRECURSOR CONCEPT - A CASE-STUDY OF GALLIUM-ARSENIDE [J].

COWLEY, AH ;

JONES, RA .

POLYHEDRON, 1994, 13 (08) :1149-1157