SYNTHESIS OF NARROW DISPERSED LINEAR POLYETHYLENE AND BLOCK-COPOLYMERS FROM POLYCYCLOBUTENE

被引：53

作者：

WU, Z ^{[1
]}

GRUBBS, RH ^{[1
]}

机构：

[1] CALTECH,ARNOLD & MABEL BECKMAN LABS CHEM SYNTHESIS,PASADENA,CA 91125

来源：

MACROMOLECULES | 1994年 / 27卷 / 23期

关键词：

D O I：

10.1021/ma00101a002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Near monodispersed linear polyethylene can be synthesized y hydrogenation of polybutadiene prepared by the living ring-opening metathesis polymerization (ROMP) of cyclobutene. The polyethylene is highly crystalline, as determined by powder X-ray diffraction, and defect free, as shown by spectroscopic data. Living polycyclobutene can also react with anthracene dialdehyde to give a labeled polymer and with norbornene to produce a block copolymer.

引用

页码：6700 / 6703

页数：4

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