FACILE RETRO-[1,4]-BROOK REARRANGEMENT OF A [(2-SILOXYCYCLOPENTYL)METHYL]LITHIUM SPECIES

被引：22

作者：

JIANG, XL ^{[1
]}

BAILEY, WF ^{[1
]}

机构：

[1] UNIV CONNECTICUT,DEPT CHEM,STORRS,CT 06269

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1021/om00012a042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [1,4]-O --> C migration of the TBDMS group in the [(2-(tert-butyldimethylsiloxcy)cyclopentyl)- methyl]lithium system (1 and 2) has been found to be confined to the cis-isomer (1).

引用

页码：5704 / 5707

页数：4

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