REACTION FIELD SIMULATIONS OF THE VAPOR-LIQUID-EQUILIBRIA OF DIPOLAR FLUIDS - DOES THE REACTION FIELD DIELECTRIC-CONSTANT AFFECT THE COEXISTENCE PROPERTIES

被引：41

作者：

GARZON, B ^{[1
]}

LAGO, S ^{[1
]}

VEGA, C ^{[1
]}

机构：

[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT QUIM FIS,E-28040 MADRID,SPAIN

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 231卷 / 4-6期

关键词：

D O I：

10.1016/0009-2614(94)01298-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vapor-liquid equilibria of two Stockmayer fluids have been obtained by computer simulations in the Gibbs ensemble. The long-range dipolar interactions have been considered within the reaction field geometry. Two different criteria for the reaction field dielectric constant, epsilon(RF), have been applied. It is shown that epsilon(RF) does not significantly affect either the coexistence properties or the structure of coexisting phases for the simulated systems.

引用

页码：366 / 372

页数：7

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