EVIDENCE FOR RATE-DETERMINING C-C BOND HETEROLYSIS IN THE CONDENSED PHASE THERMAL-DECOMPOSITION OF POLYNITROETHYL COMPOUNDS

被引：10

作者：

ADOLPH, HG

机构：

[1] US Naval Surface Weapons Cent,, Silver Spring, MD, USA, US Naval Surface Weapons Cent, Silver Spring, MD, USA

来源：

COMBUSTION AND FLAME | 1987年 / 70卷 / 03期

关键词：

HYDROCARBONS; -; Combustion;

D O I：

10.1016/0010-2180(87)90113-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal stability data for a number of cyanodinitroethyl compounds and some new trinitroethyl compounds are presented. Interpretation of this data in terms of the molecular structures present requires the assumption of a new mechanism for the thermal decomposition of such compounds, involving C-C rather than C-N bond scission. The scope of the new mechanism is discussed briefly.

引用

页码：343 / 347

页数：5

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