THE MEASUREMENT OF ENANTIOPURITY USING PHOSPHORUS-NMR

被引：16

作者：

WELCH, CJ

机构：

[1] Department of Organic Pharmaceutical Chemistry, Uppsala Biomedical Centre, Uppsala University, S 751 23 Uppsala

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(00)82011-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enantiopurity of various alcohols can be determined using phosphorus-NMR by observing the signals from the trialkyl phosphites produced by the reaction of phosphorus trichloride and the alcohol. The enantiomeric excess can be determined to within 2% using this method.

引用

页码：1127 / 1132

页数：6

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