NITROSYL SUBSTITUTED HYDRIDE COMPLEXES - AN ACTIVATED CLASS OF COMPOUNDS

被引：45

作者：

BERKE, H

BURGER, P

机构：

[1] Anorganisch - Chemisches Institute, Universilat Zurich, CH-8057 Zurich

来源：

COMMENTS ON INORGANIC CHEMISTRY | 1994年 / 16卷 / 05期

关键词：

METAL HYDRIDES; METAL NITROSYL HYDRIDE COMPLEXES; ALKYNE INSERTION; HYDRIDE TRANSFER; CARBONYL REDUCTION; METAL HYDROGEN BOND IONICITY;

D O I：

10.1080/02603599408035773

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The activation of metal hydrogen bonds toward alkyne insertion and carbonyl reduction in NO substituted transition metal hydride complexes is discussed. MO theoretical treatment elucidates a genuine nitrosyl effect and enhanced hydricity for this class of compounds. This is traced in NMR based M-H bond ionicity measurements and reactivity studies.

引用

页码：279 / 312

页数：34

共 104 条

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