A PROCEDURE FOR THE OXIDATIVE DIMERIZATION OF ALIPHATIC 1-ALKYNES

被引：17

作者：

BRANDSMA, L

VERKRUIJSSE, HD

WALDA, B

机构：

[1] Department of Preparative Organic Chemistry of the University, Debye Institute, 3584 CH Utrecht

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 01期

关键词：

D O I：

10.1080/00397919108020801

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aliphatic 1-alkynes RC = CH (R = alkyl) are readily converted into diynes R = CC = CR, by introducing oxygen into a mixture of the acetylene and pyridine using copper(I)bromide as a catalyst and 1,8-diazabicyclo[5.4.0] undec-7-ene as a co-catalyst.

引用

页码：137 / 139

页数：3