ISOTROPIC AND SOLID-STATE ESR-SPECTRA OF THE RADICAL ION-PAIRS OF 2,4,6-TRI-TERT-BUTYL THIOBENZALDEHYDE

被引：1

作者：

ALBERTI, A ^{[1
]}

PEDULLI, GF ^{[1
]}

PLACUCCI, G ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM ORGAN A MANGINI,I-40127 BOLOGNA,ITALY

来源：

JOURNAL OF MAGNETIC RESONANCE | 1991年 / 93卷 / 01期

关键词：

D O I：

10.1016/0022-2364(91)90031-N

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The sodium and potassium radical ion pairs of 2,4,6-tri-tert-butyl thiobenzaldehyde and of its ring-deuterated analog have been generated in ethereal solutions and studied by means of electron spin resonance spectroscopy. From the magnitude of the 13C hyperfine splitting it has been inferred that in this radical anion the deviation of the aromatic ring from coplanarity with the CHS plane is smaller than that in the diamagnetic precursor. The solid-state spectrum of the deuterated species has also been interpreted and the g and proton hyperfine tensors have been determined. © 1991.

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页码：63 / 70

页数：8

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