SOLVENT EFFECTS IN RADICAL COPOLYMERIZATION BETWEEN HYDROPHILIC AND HYDROPHOBIC MONOMERS - 2-HYDROXYETHYL METHACRYLATE AND LAURYL METHACRYLATE

被引：37

作者：

ITO, K ^{[1
]}

UCHIDA, K ^{[1
]}

KITANO, T ^{[1
]}

YAMADA, E ^{[1
]}

MATSUMOTO, T ^{[1
]}

机构：

[1] NIPPON OIL & FATS CO LTD,TSUKUBA LAB,TSUKUBA,IBARAKI 30026,JAPAN

来源：

POLYMER JOURNAL | 1985年 / 17卷 / 06期

关键词：

COPOLYMERS; -; MONOMERS; SOLVENTS;

D O I：

10.1295/polymj.17.761

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical copolymerization of 2-hydroxyethyl methacrylate (HEMA) and lauryl methacrylate was investigated at 60 degree C with alpha , alpha prime -azobisisobutyronitrile in benzene, tetrahydrofuran, tert-butylalcohol, and dimethylformamide. HEMA was found to have an abnormally high, apparent monomer reactivity ratio in benzene, corresponding to its high aggregation tendency in this solvent as a result of hydrogen-bonding. The apparent reactivity ratios are more or less close to azeotropic unity in the other solvents. The solution behavior of monomers is proposed as a factor in the copolymerization between hydrophilic and hydrophobic monomers.

引用

页码：761 / 766

页数：6

共 17 条

[1]

BRANDRUP J, 1975, POLYM HDB, V2, P396

[2] SYNTHESIS AND INTERFACIAL CHARACTERIZATION OF GRAFT AND RANDOM CO-POLYMERS OF STYRENE AND 2-HYDROXYETHYL METHACRYLATE [J].

ITO, K ;

MASUDA, Y ;

SHINTANI, T ;

KITANO, T ;

YAMASHITA, Y .

POLYMER JOURNAL, 1983, 15 (06) :443-448

[3]

ITO K, UNPUB POLYM J

[4] ANALYSIS OF LINEAR METHODS FOR DETERMINING COPOLYMERIZATION REACTIVITY RATIOS .1. NEW IMPROVED LINEAR GRAPHIC METHOD [J].

KELEN, T ;

TUDOS, F .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1975, A 9 (01) :1-27

[5]

KERBER R, 1966, MAKROMOLEKUL CHEM, V96, P30

[6]

KERBER R, 1971, MAKROMOLEKUL CHEM, V144, P1

[7]

KERBER R, 1967, MAKROMOLEKUL CHEM, V100, P290

[8]

LEBDUSKA L, 1984, J POLYM SCI PL, V22, P261

[9]

LUSKIN LS, 1964, ENCY POLYM SCI TECHN, V1, P246

[10]

MAYUMI J, 1980, THESIS NAGOYA U

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