AN INTERMOLECULAR MIGRATION OF TRIFLUOROMETHYL ANION

被引：6

作者：

CHAMBERS, RD ^{[1
]}

CHEBURKOV, YA ^{[1
]}

TANABE, T ^{[1
]}

VAUGHAN, JFS ^{[1
]}

机构：

[1] THREE M CO,THREE M CTR,ST PAUL,MN 55144

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 74卷 / 02期

关键词：

PERFLUORINATED ALKENES; TRIFLUOROMETHYL ANION; INTERMOLECULAR MIGRATION;

D O I：

10.1016/0022-1139(95)03270-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A fluoride-ion-induced rearrangement of a perfluorinated alkene perfluoro-4,4-dimethylpent-2-ene proceeds by migration of trifluoromethyl, giving perfluoro-2,4-dimethylpent-2-ene. It has been demonstrated that this rearrangement involves intermolecular transfer of trifluoromethyl as an anion.

引用

页码：227 / 228

页数：2

共 5 条

[1] FLUORINATED HETEROCYCLIC-COMPOUNDS [J].