IRON PENTACARBONYL-CATALYZED AMINOMETHYLATION OF ALKENES - SOME INTRIGUING OBSERVATIONS

被引：23

作者：

BRUNET, JJ

NEIBECKER, D

AGBOSSOU, F

SRIVASTAVA, RS

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

[2] UNIV PAUL SABATIER,CHIM COORDINAT LAB,CNRS,U 8241,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 87卷 / 2-3期

关键词：

ALKENES; AMINOMETHYLATION; CARBONYL COMPLEXES; IRON; PIPERIDINE;

D O I：

10.1016/0304-5102(93)E0231-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of piperidine with ethylene in the presence of Fe(CO)5, affords a mixture of N-ethyl- (minor product) and N-n-propylpiperidine (major product). Reactions conducted for 14 h at 170-degrees-C in the presence of Fe(CO)5 and water afford N-n-propylpiperidine with a turnover of 3.3 in the absence of an external source of carbon monoxide.

引用

页码：223 / 230

页数：8

共 21 条

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