FE(NCME)(3)(2+) COMPLEXES OF CHIRAL TRIPOD LIGANDS BEARING 3 DIFFERENT DONOR GROUPS - DYNAMICS AND STRUCTURE

被引：32

作者：

HEIDEL, H ^{[1
]}

SCHERER, J ^{[1
]}

ASAM, A ^{[1
]}

HUTTNER, G ^{[1
]}

WALTER, O ^{[1
]}

ZSOLNAI, L ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-69120 HEIDELBERG,GERMANY

来源：

CHEMISCHE BERICHTE | 1995年 / 128卷 / 03期

关键词：

TRIPODAL LIGANDS; CHIRAL; IRON TRIS(ACETONITRILE) TRIPOD COMPLEXES; CHIRAL TRIPHOSPHANES; CONFORMATIONAL ANALYSIS; LIGAND EXCHANGE;

D O I：

10.1002/cber.19951280314

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral tripod ligands [tripod = CH3C(CH(2)PR(2))(CH(2)PR(2)')(CH2-PR(2) ''), 1a-d] with three different donor groups react with Fe(NCMe)(6)(BF4)(2) to yield the complexes tripodFe(NC-Me)(3)(BF4)(2) (2a-d). These complexes show an idealized octahedral coordination based on a facial coordination of the triPod ligand, The asymmetry of the chiral tripod ligands 1a-d induces a differentiation of the remaining coordination sites at iron. The structure and the dynamic behaviour of the compounds 2a, b is elucidated by X-ray structural analyses and 2D-NMR techniques.-

引用

页码：293 / 301

页数：9

共 26 条

[1] ASAM A, 1993, Z NATURFORSCH B, V48, P1707
[2] ASAM A, THESIS
[3] MLEV-17-BASED TWO-DIMENSIONAL HOMONUCLEAR MAGNETIZATION TRANSFER SPECTROSCOPY
BAX, A
DAVIS, DG
[J]. JOURNAL OF MAGNETIC RESONANCE, 1985, 65 (02) : 355 - 360
[4] BAX A, 1986, J MAGN RESON, V66, P565
[5] BAX A, 1981, J MAGN RESON, V44, P565
[6] BLEICH H, 1984, J MAGN RESON, V64, P149
[7] Di Vaira M., 1982, ANGEW CHEM, V94, P338
[8] DIVAIRA M, 1982, ANGEW CHEM INT EDIT, V21, P330
[9] PREPARATION AND PROPERTIES OF SOME BIVALENT TRANSITION-METAL TETRAFLUOROBRRATE-METHYL CYANIDE COMPLEXES
HATHAWAY, BJ
HOLAH, DG
UNDERHILL, AE
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (JUN): : 2444 - &
[10] HEIDEL H, 1993, Z NATURFORSCH B, V48, P1681

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