ELECTROCRYSTALLIZATION OF FULLERIDES

被引：14

作者：

BILOW, U ^{[1
]}

JANSEN, M ^{[1
]}

机构：

[1] UNIV BONN,INST ANORGAN CHEM,D-53121 BONN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 06期

关键词：

FULLERIDES; CRYSTAL STRUCTURE; C-60(-) ANION;

D O I：

10.1002/zaac.19956210615

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fullerides P(C6H5)(4)C-60. P(C6H5)(4)Cl, P(C6H5)(4)C-60. P(C6H5)(4)Br and AS(C6H5)(4)C-60. As(C6H5)(4)Cl have been prepared by electrocrystallization. Single crystal structure determinations have shown them to be isostructural in space group I4/m with lattice constants a = 12.5731(9), c = 20.142(3) Angstrom; a = 12.5378(10), c = 20.606(5) Angstrom; a = 12.6003(11), c = 20.377(4) Angstrom, respectively. Spectroscopic and magnetic investigations prove the existence of a C-60(-) anion, showing orientational disorder in all three fullerides.

引用

页码：982 / 986

页数：5

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