CHIRAL CARBAMATES THROUGH AN ENZYMATIC ALKOXYCARBONYLATION REACTION

被引：50

作者：

POZO, M ^{[1
]}

GOTOR, V ^{[1
]}

机构：

[1] UNIV OVIEDO,FAC QUIM,DEPT QUIM ORGAN & INORGAN,E-33071 OVIEDO,SPAIN

来源：

TETRAHEDRON | 1993年 / 49卷 / 20期

关键词：

VINYL CARBONATES; ENZYMATIC ALKOXYCARBONYLATION; CHIRAL CARBAMATES; ENANTIOSELECTIVITY; LIPASES;

D O I：

10.1016/S0040-4020(01)85748-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral carbamates could be obtained by enzymatic alkoxycarbonylation with vinyl carbonates and racemic amines using Candida antarctica lipase. The enantioselectivity achieved depended on the substrate nature and the solvent.

引用

页码：4321 / 4326

页数：6

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