FORMATION OF 18-MEMBERED METALLOMACROCYCLIC RINGS BY THE SULFUR-DONOR LIGAND N,N'-ETHYLENEBIS(PYRROLIDIN-2-THIONE) IN THE COMPOUNDS [CO(EBPT)BR-2](2) AND ([CU(EBPT)(2)]PF6)(N)

被引：10

作者：

ATHERTON, Z

GOODGAME, DML

KATAHIRA, DA

MENZER, S

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ligand N,N'-ethylenebis(pyrrolidin-2-thione) (ebpt) reacts with cobalt(II) bromide to form [Co(ebpt)Br-2](2) comprising discrete 18-membered rings, and with Cu(MeCN)(4)PF6 to produce polymeric {[Cu(ebpt)(2)]PF6}(n) in which there are chains of spiro-linked 18-membered rings, the ring conformation remaining unchanged.

引用

页码：1423 / 1424

页数：2

共 15 条

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